THE POTENTIAL AND WAYS OF AGRICULTURAL BIOMASS HYDROGEN PRODUCTION ASSESSMENT
Abstract
The purpose of the article is to assess the agricultural biomass hydrogen production potential and determine the areas of technical support for the realization of this potential. The article presents a promising model of production and biofuels use of agricultural origin. According to this model, it is appropriate to produce diesel biofuel, bioethanol (in the amount necessary to ensure the mobile equipment operation), biogas, biohydrogen, generator gas, solid biofuels (rolls, fuel pellets, straw briquettes).
It is established that hydrogen production in agriculture is possible using both the method of biomass thermochemical conversion and the biomass fermentation method. When using the thermochemical method, the proportion of plant biomass is used for the production of fuel pellets. Generator gas is produced of granules. Generator gas is used to produce biohydrogen. Additionally, the biomass of plant origin proportion, as well as livestock by-products can be processed into biogas by dark fermentation. For the biohydrogen by thermochemical method production, the use of advanced gas generators is proposed, the design of which prevents the formation of solid deposits on the working surfaces in the gas formation chamber. For the biohydrogen by fermentation production, the use of rotating bioreactors is proposed.
It is established that the theoretical potential of hydrogen production of plant origin agricultural biomass by thermochemical transformation is about 4.8 billion m3 of hydrogen per year. The theoretical potential of hydrogen production by fermentation is about 1.4 billion m3 per year.
For the hydrogen theoretical potential practical implementation, further theoretical and experimental studies of both methods of obtaining hydrogen in the conditions of agricultural production are necessary. Ref. 31, fig. 9.
References
2. Rzeznik W., Mielcarek P. Agricultural biogas plants in Poland. Proceedings of 17th International Scientific Conference “Engineering for rural development”. May 23-25: Pp. 1760-1765. [in English].
3. Kukharets S.M. Pidvyshchennia enerhetychnoi avtonomnosti ahroekosystem. [Increasing the energy autonomy of agroecosystems]. Mechanical and technological bases. monograph. Zhytomyr. ZhNAEU.2016. 192 p. [in Ukrainian].
4. Ovcharuk O., Hutsol T., Ovcharuk O., Rudskyi V., Mudryk Kr., Jewiarz M., Wrobel M., Styks J. Prospects of Use of Nutrient Remains of Corn Plants on Biofuels and Production Technology of Pellets. Renewable Energy Sources. Engineering. Technology. Innovation. 01/2020. Pp. 293-300. [in English].
5. Verdade, L.M., Pina C.I., Rosalino L.M. Biofuels and biodiversity: Challenges and opportunities, Environmental Development. 2015. Pp. 64-78. [in English].
6. Gomiero T. Large-scale biofuels production: A possible threat to soil conservation and environmental services. Applied Soil Ecology. 2017. Pp. 729-736. [in English]
7. Yarosh Y.D. Enerhetychna avtonomnist ahroeoksystem. [Energy autonomy of agroeoxystems]. monograph. Zhytomyr. ZNAEU. 2020. 316 p. [in Ukrainian].
8. Golub G., Skydan O., Kukharets V., Yarosh Y., Kukharets S. The estimation of energetically self-sufficient agroecosystems model. Journal of Central European Agriculture. 2020. No. 21(1). Рp. 168-175. [in English].
9. Gas Decarbonisation Pathways 2020–2050. [Electronic resource]. URL:https://gasforclimate2050.eu/sdm_downloads /2020-gas-decarbonisation-pathways-study/ (Applying date 31.10.2020). [in English].
10. Pandey Bh., Prajapati Y.K., Sheth P.N. Recent progress in thermochemical techniques to produce hydrogen gas from biomass. A state of the art review, International Journal of Hydrogen Energy. Vol. 44. Issue 47. 2019. Pp. 25384-25415. [in English].
11. Golub G., Kukharets S., Skydan O., Yarosh Y., Chuba V., Golub V. The Optimization of the Gasifier Recovery Zone Height When Working on Straw Pellets. Іnternational Journal of Renewable Energy Research. Vol. 10. No. 2. 2020. Pp. 529-536. [in English].
12. Mac an Bhaird S., Walsh E., Hemmingway P., Maglinao A.L., Capareda S.C., McDonnell K.P. Analysis of bed agglomeration during gasification of wheat straw in a bubbling fluidised bed gasifier using mullite as bed material. Powder Technology. 2014. No. 254 Pp. 448-459. [in English].
13. Wu Z., Meng Н., Luo Z., Chen L., Zhao J., Wangv S. Performance evaluation on co-gasification of bituminous coal and wheat straw in entrained flow gasification system. International Journal of Hydrogen Energy. 2017. No. 42. Pp. 18884-18893. [in English].
14. Sarker S., Arauzo J., Nielsen H.K. Semi-continuous feeding and gasification of alfalfa and wheat straw pellets in a lab-scale fluidized bed reactor. Energy Conversion and Management. 2015. No. 99. Pp. 50-61. [in English].
15. Golub G.A., Skydan O.V., Kukharets S.M, Yarosh Y.D., Golub V.A., Chuba V.V., Sabadash O.S. Pat. 121173 Ukrayina. MPK (2006). B01J 7/00. F23C 7/00 Hazohenerator. Zayavnyk ta patentovlasnyk. Golub G.A. [Pat. 121173 Ukraine. MPK (2006). B01J 7/00. F23C 7/00. Gas generator. Applicant and patent owner Golub G.A.]. No. a201901587. zaiavl. 18.02.2019. opubl. 10.04.2020. Biul. No. 7. [in Ukrainian].
16. Roslynnytstvo Ukrainy 2019. [Crop production of Ukraine 2019]. Statystychnyi zbirnyk. Derzhavna sluzhba statystyky Ukrainy. Kyiv. 2020. 183 p. [in Ukrainian].
17. Heletukha H.H., Zhelezna T.A. Perspektyvy vykorystannia vidkhodiv silskoho hospodarstva dlia vyrobnytstva enerhii v Ukraini. [Prospects for the use of agricultural waste for energy production in Ukraine]. Analitychna zapyska BAU. 2014. No.7. 33 p. [in Ukrainian].
18. Fedorchuk Ye.M. Otsinka potentsialu tverdoi biomasy v silskomu hospodarstvi Ukrainy. [Assessment of the potential of solid biomass in agriculture of Ukraine]. Visnyk Sumskoho natsionalnoho ahrarnoho universytetu. Seriia: Ekonomika i menedzhment. 2014. Vol. 8. Pp. 48-54. [in Ukrainian].
19. Golub G., Kukharets S., Tsyvenkova N., Yarosh Ya., Chuba V. Experimental study into the influence of straw content in fuel on parameters of generator gas. Eastern-European Journal of Enterprise Technologies. 2018. No. 5/8(95). Pp. 76-86. [in English].
20. Li Q., Song G., Xiao J., Sun T., Yang K. Exergy analysis of biomass staged-gasification for hydrogen-rich syngas. International Journal of Hydrogen Energy. 2019. Vol. 44. Issue 5. Pp. 2569-2579. [in English].
21. Seçer A., Küçet N., Fakı E., Hasanoğlu A. Comparison of co–gasification efficiencies of coal, lignocellulosic biomass and biomass hydrolysate for high yield hydrogen production, International Journal of Hydrogen Energy. 2018. Vol. 43. Issue 46. Pp. 21269-21278. [in English].
22. Baeyens J., Zhang H., Nie J., Appels L., Dewil R., Ansart R., Deng Y. Reviewing the potential of bio-hydrogen production by fermentation. Renewable and Sustainable Energy Reviews. 2020. Vol. 13. [in English].
23. Cao L., Yu I.K.M., Xiong X., Tsang D.C.W., Zhang S., Clark J.H., Ok Y.S. Biorenewable hydrogen production through biomass gasification: A review and future prospects. Environmental Research. 2020. Vol. 186. [in English].
24. Ghimire A., Frunzo L., Pirozzi F., Trably E., Escudie R., Lens P.N.L., Esposito G. A review on dark fermentative biohydrogen production from organic biomass: Process parameters and use of by-products. Applied Energy. 2015. No. 144. Pp. 73-95. [in English].
25. Golub G.A., Skydan O.V., Kukharets S.M., Marus O.A. Substantiation of motion parameters of the substrate particles in the rotating digesters. INMATEH – Agricultural Engineering. 2019. Vol. 57. No. 1. Pp. 179-186. [in English].
26. Golub G.A., Kukharets S.M. Pat. 110077 Ukraina. MPK C02F 11/04. C02F 3/28. Metantenk. Zaiavnyk i patentovlasnyk Nats. un.-t. bioresursiv i pryrodokrystuvannia Ukrainy. [Pat. 110077 Ukraine. MPK C02F 11/04. C02F 3/28. Methanetank. Applicant and patent owner Nat. un.-t. bioresources and nature management of Ukraine]. No. a201409259. zaiavl. 19.08.2014. data publikatsii 10.11.2015. Biul. No. 21. [in Ukrainian].
27. Tvarynnytstvo Ukrainy 2019. [Livestock of Ukraine 2019. Statistical collection]. Statystychnyi zbirnyk. Derzhavna sluzhba statystyky Ukrainy. Kyiv. 2020. 158 p. [in Ukrainian].
28. Hrytsai A.H., Masliukova Z.V. Otsinka enerhetychnoho potentsialu biohazu Ukrainy. [Assessment of energy potential of biogas of Ukraine]. Naukovi horyzonty. 2019. No. 10(83). Pp. 58-63. [in Ukrainian].
32. Łukajtis R., Hołowacz I., Kucharska K.,.Glinka M, Rybarczyk P., Przyjazny A., Kamiński M. Hydrogen production from biomass using dark fermentation. Renewable and Sustainable Energy Reviews. 2018. Vol. 91. Pp. 665-694. [in English].
33. Kumar G., Shobana S., Nagarajan D., Lee D.-J., Lee K.-S., Lin C.-Y., Chang J.-S. Biomass based hydrogen production by dark fermentation - recent trends and opportunities for greener processes. Current Opinion in Biotechnology. 2018. Vol. 50. Pp. 136-145. [in English].
29. Kukharets S.M., Holub G.A. Syrovynna baza ta efektyvnist vyrobnytstva biohazu. [Raw material base and efficiency of biogas production]. Nauk. visn. Nats. un-tu bioresursiv i pryrodokorystuvannia Ukrainy. Ser. Tekhnika ta enerhetyka APK. 2015. Vol. 212. No. 1. Pp. 11-20. [in Ukrainian].